Diffusion Processes in Semiconductor Technology

Diffusion of impurity atoms in silicon during processing is important for the electrical characteristics of silicon devices. Various ways of introducing dopants into silicon by diffusion are used and have been studied with the goals of controlling dopant distribution, total dopant concentration, uniformity, and reproducibility.

Diffusion is used to form base, emitter, and collector regions in bipolar device processing, to form source, drain and channel regions, and to dope polysilicon in MOS processing. Dopant atoms that span a wide range of concentrations can be introduced into silicon in many ways. The most commonly used methods are
  1. Diffusion from a chemical source in a vapor form at high temperatures,
  2. Diffusion from a doped-oxide source, and
  3. Diffusion and annealing from an ion-implanted layer (see ion implantation).

The electrical activation of ion-implanted species is carried out by annealing. This causes a redistribution of the impurity atoms which should be as low as possible. In order to optimize the electrical behavior of the device, it is important to know how the impurities redistribute during the anneal. The development of appropriate models and simulation programs to predict the diffusion is one major topic in semiconductor technology research.


Vertical furnace which can be used for diffusion, oxidation,
or for chemical vapor deposition (CVD) processes.

Below we show several examples of how dopants redistribute during diffusion processes. The simulations have been carried out with the 1D process simulator ICECREM from FhG-IIS-B.

You can have a look at the following 1D simulations:
Diffusion from a source with constant concentration (144 kB)
Diffusion of a shallow profile in a semi-infinite half-space. (141 kB)
Redistribution of boron after ion implantation (192 kB)
Boron diffusion in oxidizing atmosphere (182 kB)
Phosphorus diffusion in oxidizing atmosphere (179 kB)
Codiffusion of arsenic and boron (178 kB)
Diffusion of boron at high concentrations (148 kB)